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{2,6-Bis[(2,6-diphenyl-phosphan-yl)-oxy]-4-fluoro-phenyl-κP,C,P'}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathia-zin-3-ido-κN)palladium(II).

ABSTRACT: The title acesulfamate complex, [Pd(C(30)H(22)FO(2)P(2))(C(4)H(4)NO(4)S)], contains a four-coordinate Pd(II) ion with the expected, although relatively distorted, square-planar geometry where the four L-Pd-L angles range from 79.58 (8) to 102.47 (7)°. The acesulfamate ligand is N-bound to Pd [Pd-N = 2.127 (2) Å] with a dihedral angle of 76.35 (6)° relative to the square plane. Relatively long phen-yl-acesulfamate C-H⋯O and phen-yl-fluorine C-H⋯F inter-actions consolidate the crystal packing.

SUBMITTER: Wicker BF

PROVIDER: S-EPMC3051636 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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{2,6-Bis[(2,6-diphenyl-phosphan-yl)-oxy]-4-fluoro-phenyl-κP,C,P'}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathia-zin-3-ido-κN)palladium(II).

Wicker Benjamin F BF Seaman Rachel R Hoffman Norris W NW Davis James H JH Sykora Richard E RE

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

The title acesulfamate complex, [Pd(C(30)H(22)FO(2)P(2))(C(4)H(4)NO(4)S)], contains a four-coordinate Pd(II) ion with the expected, although relatively distorted, square-planar geometry where the four L-Pd-L angles range from 79.58 (8) to 102.47 (7)°. The acesulfamate ligand is N-bound to Pd [Pd-N = 2.127 (2) Å] with a dihedral angle of 76.35 (6)° relative to the square plane. Relatively long phen-yl-acesulfamate C-H⋯O and phen-yl-fluorine C-H⋯F inter-actions consolidate the crystal packing. ...[more]

PMID: 21522930

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