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[?-1,2-Bis(diphenyl-phosphan-yl)benzene-?P:P']bis-[chloridogold(I)].

ABSTRACT: In the crystal structure of the non-solvate form of the title compound, [Au(2)Cl(2)(C(30)H(24)P(2))], two almost linear P-Au(I)-Cl units [175.87?(3) and 171.48?(3)°] are in a skewed arrangement with a Cl-Au?Au-Cl torsion angle of -65.29?(3)° so as to form an intra-molecular Au?Au inter-action [3.0563?(2)?Å]. The complex mol-ecules are connected each other through inter-molecular C-H?? inter-actions, giving a sheet structure parallel to the bc plane.

SUBMITTER: Yoshinari N

PROVIDER: S-EPMC3050393 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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[μ-1,2-Bis(diphenyl-phosphan-yl)benzene-κP:P']bis-[chloridogold(I)].

Yoshinari Nobuto N Kitani Naoki N Tsukuda Toshiaki T Konno Takumi T

Acta crystallographica. Section E, Structure reports online 20101224 Pt 1

In the crystal structure of the non-solvate form of the title compound, [Au(2)Cl(2)(C(30)H(24)P(2))], two almost linear P-Au(I)-Cl units [175.87 (3) and 171.48 (3)°] are in a skewed arrangement with a Cl-Au⋯Au-Cl torsion angle of -65.29 (3)° so as to form an intra-molecular Au⋯Au inter-action [3.0563 (2) Å]. The complex mol-ecules are connected each other through inter-molecular C-H⋯π inter-actions, giving a sheet structure parallel to the bc plane. ...[more]

PMID: 21522532

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