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{1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-?N,O,S}diphenyl-tin(IV).

ABSTRACT: The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(12)H(9)N(3)OS)], contains two independent mol-ecules with almost identical configurations. In each mol-ecule, the Sn(IV) atom is coordinated by O, N and S atoms from a (2-oxido-1-naph-thaldehyde)-thio-semicarbazonato ligand and two C atoms from phenyl rings in a distorted trigonal-bipyramidal geometry. Weak inter-molecular N-H?O and N-H?S hydrogen bonds link four mol-ecules into a centrosymmetric tetra-mer. The crystal packing exhibits short inter-molecular S?S contacts of 3.335?(3)?Å.

SUBMITTER: Cui J 

PROVIDER: S-EPMC3051660 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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{1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κN,O,S}diphenyl-tin(IV).

Cui Jichun J   Ruan Hong H   Qiao Yanling Y   Yin Handong H  

Acta crystallographica. Section E, Structure reports online 20110108 Pt 2

The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(12)H(9)N(3)OS)], contains two independent mol-ecules with almost identical configurations. In each mol-ecule, the Sn(IV) atom is coordinated by O, N and S atoms from a (2-oxido-1-naph-thaldehyde)-thio-semicarbazonato ligand and two C atoms from phenyl rings in a distorted trigonal-bipyramidal geometry. Weak inter-molecular N-H⋯O and N-H⋯S hydrogen bonds link four mol-ecules into a centrosymmetric tetra-mer. The crystal packing exhibit  ...[more]

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