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Dimeth-yl(4'-pyridyl-2,2':6',2''-terpyridine-?N,N,N)bis(thio-cyanato-?N)tin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(CH(3))(2)(NCS)(2)(C(20)H(14)N(4))], is N,N',N''-chelated by the terpyridine part of the N-heterocycle. The Sn atom exists in a trans-C(2)SnN(5) penta-gonal-bipyramidal geometry [C-Sn-C = 173.66?(8)°] with the methyl groups in axial and the N atoms in equatorial positions.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3051620 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Dimeth-yl(4'-pyridyl-2,2':6',2''-terpyridine-κN,N,N)bis(thio-cyanato-κN)tin(IV).

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110115 Pt 2

The Sn atom in the title compound, [Sn(CH(3))(2)(NCS)(2)(C(20)H(14)N(4))], is N,N',N''-chelated by the terpyridine part of the N-heterocycle. The Sn atom exists in a trans-C(2)SnN(5) penta-gonal-bipyramidal geometry [C-Sn-C = 173.66 (8)°] with the methyl groups in axial and the N atoms in equatorial positions. ...[more]

PMID: 21522874

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