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8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(pyridine-2-carboxyl-ato-?N,O)stannate(IV).

ABSTRACT: In the reaction of pyridine-2-carb-oxy-lic acid and stannic chloride in the presence of 2-methyl-8-hy-droxy-quinoline, the 2-methyl-8-hy-droxy-quinoline is protonated, yielding the title salt, (C(10)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxyl-ate in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an O-H?O hydrogen bond.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3051689 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(pyridine-2-carboxyl-ato-κN,O)stannate(IV).

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

In the reaction of pyridine-2-carb-oxy-lic acid and stannic chloride in the presence of 2-methyl-8-hy-droxy-quinoline, the 2-methyl-8-hy-droxy-quinoline is protonated, yielding the title salt, (C(10)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxyl-ate in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an O-H⋯O hydrogen bond. ...[more]

PMID: 21522895

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