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Di-?-methanolato-?O:O-bis[tri-chlorido(dimethyl-formamide-?O)tin(IV)].

ABSTRACT: The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa-coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa-hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl-formamide mol-ecule. The complex mol-ecules are connected by weak C-H?Cl hydrogen bonds into a two-dimensional supra-molecular network parallel to (10).

SUBMITTER: Zhang Q

PROVIDER: S-EPMC3051740 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Di-μ-methanolato-κO:O-bis[tri-chlorido(dimethyl-formamide-κO)tin(IV)].

Zhang Qijun Q Yin Handong H Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20110108 Pt 2

The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa-coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa-hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl-formamide mol-ecule. The complex mol-ecules are connected by weak C-H⋯Cl hydrogen bonds into a two-dimensional supra-mol ...[more]

PMID: 21522830

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