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Trans-Di-chlorido-bis-(dimethyl sulfoxide-?O)bis-(4-fluoro-benzyl-?C1)tin(IV): crystal structure and Hirshfeld surface analysis.

ABSTRACT: The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H?F, C-H?Cl and C-H?? inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl?H/H?Cl and F?H/H?F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.

SUBMITTER: Amin NABM

PROVIDER: S-EPMC5418780 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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trans-Di-chlorido-bis-(dimethyl sulfoxide-κO)bis-(4-fluoro-benzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis.

Amin Nur Adibah Binti Mohd NABM Hussen Rusnah Syahila Duali RSD Lee See Mun SM Halcovitch Nathan R NR Jotani Mukesh M MM Tiekink Edward R T ERT

Acta crystallographica. Section E, Crystallographic communications 20170407 Pt 5

The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective infl ...[more]

PMID: 28529772

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