Browse
Submit Data
Databases
API
Help

Dataset Information

24 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Di-?-chlorido-bis[chloridobis(dimethyl sulfoxide-?O)tin(II)].

ABSTRACT: The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn?Cl [3.691?(2)?Å] inter-actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta-coordinated and have a distorted octa-hedral ?-SnCl(3)O(2) coordination geometry. The O atoms from the dimethyl sulfoxide mol-ecules occupy trans positions, while the Cl atoms exhibit a meridional arrangement.

SUBMITTER: Barbul I

PROVIDER: S-EPMC3100018 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)].

Barbul Ioana I Varga Richard A RA Silvestru Cristian C

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn⋯Cl [3.691 (2) Å] inter-actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta-coordinated and have a distorted octa-hedral Ψ-SnCl(3)O(2) coordination geometry. The O atoms from the dimethyl sulfoxide mol-ecules occupy trans positions, while the Cl atoms exhibit a meridional arrangement. ...[more]

PMID: 21753997

Similar Datasets

Di-μ-chlorido-bis-[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)].

Project description:In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a penta-gonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O atoms from non-adjacent dimethyl sulfoxides and three chloride ions (of which two chlorides are bridging). The compound is of inter-est as an anhydrous starting material of the uran-yl(VI) ion.

| S-EPMC2915060 | biostudies-literature

Di-chlorido-dimethyl-bis-(thio-urea-κS)tin(IV).

Project description:The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-mol-ecules in the asymmetric unit. Both mol-ecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octa-hedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thio-urea S atoms. In the crystal, mol-ecules are linked via N-H⋯Cl and N-H⋯S hydrogen bonds, forming a three-dimensional structure.

| S-EPMC3998430 | biostudies-literature

trans-Di-chlorido-bis-(dimethyl sulfoxide-κO)bis-(4-fluoro-benzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis.

Project description:The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.

| S-EPMC5418780 | biostudies-literature

Chlorido(dimethyl sulfoxide-κO)triphenyl-tin(IV).

Project description:In the title compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], the Sn(IV) atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide mol-ecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent mol-ecules are linked through inter-molecular C-H⋯Cl hydrogen bonds, weak C-H⋯π inter-actions and π-π inter-actions [centroid-centroid distance = 3.934 (3) Å. An intra-molecular C-H⋯π inter-action is also observed.

| S-EPMC2971969 | biostudies-literature

Bis(chlorido)(dimethyl-sulfoxide-?O)barium(II).

Project description:The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl-sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa-hedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are inter-connected by the DMSO mol-ecules, forming a three-dimensional network.

| S-EPMC3515089 | biostudies-other

Di-μ-methanolato-κO:O-bis[tri-chlorido(dimethyl-formamide-κO)tin(IV)].

Project description:The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa-coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa-hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl-formamide mol-ecule. The complex mol-ecules are connected by weak C-H⋯Cl hydrogen bonds into a two-dimensional supra-molecular network parallel to (10).

| S-EPMC3051740 | biostudies-literature

Monoclinic polymorph of chlorido-(dimethyl sulfoxide-κO)tri-phenyl-tin(IV).

Project description:The crystal structure of the title tin complex, [Sn(C6H5)3Cl(C2H6OS)], (I), has been reported with one mol-ecule in the asymmetric unit in an ortho-rhom-bic cell [Kumar et al. (2009 ▸). Acta Cryst. E65, m1602-m1603]. While using SnPh3Cl as a starting material for a reaction for which the products were recrystallized over a very long time (six months) from dimethyl sulfoxide (DMSO), a new polymorph was obtained for (I), with two independent mol-ecules in the asymmetric unit of a monoclinic cell. The coordination geometry of the Sn centres remains unchanged, with the Cl- ion and the DMSO mol-ecule in the apical positions and the phenyl C atoms in the equatorial positions of a trigonal bipyramid. The main difference between the polymorphs is the relative orientation of the phenyl rings in the equatorial plane, reflecting a degree of free rotation of these groups about their Sn-C bonds. In the crystal, mol-ecules are linked into [010] chains mediated by weak C-H⋯O inter-actions.

| S-EPMC5956328 | biostudies-literature

Tetra-chloridobis(dibenzyl sulfoxide-?O)tin(IV).

Project description:The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa-hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl?S = 3.320?(1) and 3.376?(1)?Å]; the Sn-Cl bonds involving these two Cl atoms are longer than the other two Sn-Cl bonds.

| S-EPMC3120392 | biostudies-literature

Bis(dimethyl sulfoxide-?O)bis-(mercapto-acetato-?O,S)tin(IV).

Project description:In the title compound, [Sn(C(2)H(2)O(2)S)(2)(C(2)H(6)OS)(2)], the mercaptoacetato ligands chelate to Sn(IV) through S and one O atoms. The metal centre is also coordinated by two dimethyl sulfoxide (DMSO) ligands through the O atom, leading to an overall distorted octahedral coordination environment for the Sn(IV) atom. The mol-ecular adduct lies on a twofold rotation axis.

| S-EPMC2971123 | biostudies-literature

Crystal structure of di-μ-isobutyrato-κ(4) O:O'-bis-[cis-di-chlorido-(dimethyl sulfoxide-κS)rhenium(III)].

Project description:The title compound, [Re2(C3H7COO)2Cl4{(CH3)2SO}2], comprises binuclear complex mol-ecules [Re-Re = 2.24502 (13) Å] involving cis-oriented double carboxyl-ate bridges, four equatorial chloride ions and two weakly bonded O atoms from dimethyl sulfoxide ligands in the axial positions at the Re(III) atoms. In the crystal, mol-ecules are linked into corrugated layers parallel to (101) by very weak C-H⋯Cl and C-H⋯O hydrogen-bonding inter-actions. C-H⋯Cl hydrogen bonding provides the links between layers to consolidate a three-dimensional framework.

| S-EPMC4647422 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data