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Di-?-chlorido-bis[chloridobis(dimethyl sulfoxide-?O)tin(II)].

ABSTRACT: The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn?Cl [3.691?(2)?Å] inter-actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta-coordinated and have a distorted octa-hedral ?-SnCl(3)O(2) coordination geometry. The O atoms from the dimethyl sulfoxide mol-ecules occupy trans positions, while the Cl atoms exhibit a meridional arrangement.

SUBMITTER: Barbul I

PROVIDER: S-EPMC3100018 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)].

Barbul Ioana I Varga Richard A RA Silvestru Cristian C

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn⋯Cl [3.691 (2) Å] inter-actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta-coordinated and have a distorted octa-hedral Ψ-SnCl(3)O(2) coordination geometry. The O atoms from the dimethyl sulfoxide mol-ecules occupy trans positions, while the Cl atoms exhibit a meridional arrangement. ...[more]

PMID: 21753997

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