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Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-?O,O',O''}calcium bis(perchlorate) acetonitrile disolvate.

ABSTRACT: The title complex, [Ca(C(27)H(30)N(4)O(3))(2)](ClO(4))(2)·2CH(3)CN, is composed of centrosymmetric (CaL(2))(2+) cations [L = tris-(2-hy-droxy-benzoyl-amino-eth-yl)amine = H(3)saltren], uncoordin-ated perchlorate anions and acetonitrile solvent mol-ecules. The calcium ion is six-coordinated and is bonded to all phen-oxy O atoms from both zwitterionic saltren mol-ecules. There are strong intra-molecular N-H?O hydrogen bonds. The cations are linked into chains via weak inter-molecular C-H?O hydrogen bonds and C-H?? and ?-? stacking inter-actions [centroid-centroid distances = 3.306?(3) and 3.415?(3)?Å].

SUBMITTER: Kose M

PROVIDER: S-EPMC3051774 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κO,O',O''}calcium bis(perchlorate) acetonitrile disolvate.

Kose Muhammet M McKee Vickie V McKee Vickie V

Acta crystallographica. Section E, Structure reports online 20110108 Pt 2

The title complex, [Ca(C(27)H(30)N(4)O(3))(2)](ClO(4))(2)·2CH(3)CN, is composed of centrosymmetric (CaL(2))(2+) cations [L = tris-(2-hy-droxy-benzoyl-amino-eth-yl)amine = H(3)saltren], uncoordin-ated perchlorate anions and acetonitrile solvent mol-ecules. The calcium ion is six-coordinated and is bonded to all phen-oxy O atoms from both zwitterionic saltren mol-ecules. There are strong intra-molecular N-H⋯O hydrogen bonds. The cations are linked into chains via weak inter-molecular C-H⋯O hydroge ...[more]

PMID: 21522833

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