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Catena-Poly[[(1,10-phenanthroline-?N,N')copper(I)]-?-thio-cyanato-?N:S].


ABSTRACT: In the title complex, [Cu(NCS)(C(12)H(8)N(2))](n), the Cu(I) ion is in a distorted tetra-hedral CuN(3)S coordination geometry. The thio-cyanate ligand acts as bridging ligand, forming chains along [100]. A crystallographic mirror plane runs through the Cu(I) ion, the thio-cyanate ligand and the middle of the phenanthroline ligand.

SUBMITTER: Li H 

PROVIDER: S-EPMC2983214 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[(1,10-phenanthroline-κN,N')copper(I)]-μ-thio-cyanato-κN:S].

Li Hong H   Zhang Shi Guo SG  

Acta crystallographica. Section E, Structure reports online 20100908 Pt 10


In the title complex, [Cu(NCS)(C(12)H(8)N(2))](n), the Cu(I) ion is in a distorted tetra-hedral CuN(3)S coordination geometry. The thio-cyanate ligand acts as bridging ligand, forming chains along [100]. A crystallographic mirror plane runs through the Cu(I) ion, the thio-cyanate ligand and the middle of the phenanthroline ligand. ...[more]

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