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Bis(?-N-nitroso-N-phenyl-hydroxy-laminato)-?O,O':O';?O':O,O'-bis-[(N-nitroso-N-phenyl-hydroxy-laminato-?O,O')lead(II)].

ABSTRACT: The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O'-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted ?-octa-hedral; if another two longer inter-molecular Pb?O inter-actions [at 2.955?(1) and 3.099?(1)?Å] are considered, the geometry is a distorted ?-square anti-prism.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3052047 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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Bis(μ-N-nitroso-N-phenyl-hydroxy-laminato)-κO,O':O';κO':O,O'-bis-[(N-nitroso-N-phenyl-hydroxy-laminato-κO,O')lead(II)].

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110226 Pt 3

The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O'-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octa-hedral; if another two longer inter-molecular Pb⋯O inter-actions [at 2.955 (1) and 3.099 (1) Å] are considered, the geometry is a distorted Ψ-square anti-prism. ...[more]

PMID: 21522298

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