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5-Bromo-3-(indan-1-yl-oxy)pyridin-2-amine.

ABSTRACT: The title compound, C(14)H(13)BrN(2)O, was obtained by reaction of indan-1-yl methane-sulfonate with 2-amino-5-bromo-pyridin-3-ol in the presence of caesium carbonate. The indane ring system is approximately planar [all but one of the C atoms are coplanar within 0.03?Å, the latter atom being displaced by 0.206?(2)?Å from the mean plane through the remaining atoms] and forms a dihedral angle of 58.41?(4)° with the pyridine ring. In the crystal, centrosymmetrically related mol-ecules are linked into dimers by N-H?N hydrogen bonds.

SUBMITTER: Cho-Schultz S

PROVIDER: S-EPMC3052095 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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5-Bromo-3-(indan-1-yl-oxy)pyridin-2-amine.

Cho-Schultz Sujin S Kath John C JC Moore Curtis C Rheingold Arnold L AL Yanovsky Alex A

Acta crystallographica. Section E, Structure reports online 20110219 Pt 3

The title compound, C(14)H(13)BrN(2)O, was obtained by reaction of indan-1-yl methane-sulfonate with 2-amino-5-bromo-pyridin-3-ol in the presence of caesium carbonate. The indane ring system is approximately planar [all but one of the C atoms are coplanar within 0.03 Å, the latter atom being displaced by 0.206 (2) Å from the mean plane through the remaining atoms] and forms a dihedral angle of 58.41 (4)° with the pyridine ring. In the crystal, centrosymmetrically related mol-ecules are linked in ...[more]

PMID: 21522402

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