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N-(Pyridin-2-ylmeth-yl)pyridin-2-amine.

ABSTRACT: The title compound, C(11)H(11)N(3), crystallizes with two mol-ecules (A and B) in the asymmetric unit. The geometries of both mol-ecules are very similar, with the exception of the torsion angles of the inter-ring chains; the values for C-N-C-C are 67.4?(5) and -69.3?(5)° for mol-ecules A and B, respectively. The dihedral angles between the pyridyl ring planes are 84.0?(2) and 83.2?(2)° for mol-ecules A and B, respectively. In the crystal, weak inter-molecular N-H?N hydrogen bonds and C-H?? inter-actions contribute to the stabilization of the packing.

SUBMITTER: Moon SH

PROVIDER: S-EPMC3120475 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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N-(Pyridin-2-ylmeth-yl)pyridin-2-amine.

Moon Suk-Hee SH Kim Tae Ho TH Park Ki-Min KM

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The title compound, C(11)H(11)N(3), crystallizes with two mol-ecules (A and B) in the asymmetric unit. The geometries of both mol-ecules are very similar, with the exception of the torsion angles of the inter-ring chains; the values for C-N-C-C are 67.4 (5) and -69.3 (5)° for mol-ecules A and B, respectively. The dihedral angles between the pyridyl ring planes are 84.0 (2) and 83.2 (2)° for mol-ecules A and B, respectively. In the crystal, weak inter-molecular N-H⋯N hydrogen bonds and C-H⋯π inte ...[more]

PMID: 21754749

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