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(2-{[1-(Pyridin-2-yl)ethyl-idene]amino-meth-yl}pyridine-?N,N',N'')bis-(thio-cyanato-?N)zinc.

ABSTRACT: The complete mol-ecule of the title mononuclear zinc(II) complex, [Zn(NCS)(2)(C(13)H(13)N(3))], is generated by crystallographic twofold symmetry, with the metal atom lying on the rotation axis. The pendant methyl group of the ligand is statistically disordered over two sites. The Zn(2+) cation is coordinated by the N,N',N''-tridentate Schiff base ligand, and by two thio-cyanate N atoms, forming a distorted ZnN(5) trigonal-bipyramidal geometry.

SUBMITTER: Wang CY

PROVIDER: S-EPMC3247537 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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(2-{[1-(Pyridin-2-yl)ethyl-idene]amino-meth-yl}pyridine-κN,N',N'')bis-(thio-cyanato-κN)zinc.

Wang Chen-Yi CY Li Jing-Fen JF Wu Xiang X Tu Hai-Yu HY Zhu Pei-Fei PF

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

The complete mol-ecule of the title mononuclear zinc(II) complex, [Zn(NCS)(2)(C(13)H(13)N(3))], is generated by crystallographic twofold symmetry, with the metal atom lying on the rotation axis. The pendant methyl group of the ligand is statistically disordered over two sites. The Zn(2+) cation is coordinated by the N,N',N''-tridentate Schiff base ligand, and by two thio-cyanate N atoms, forming a distorted ZnN(5) trigonal-bipyramidal geometry. ...[more]

PMID: 22219842

Similar Datasets

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