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[N,N,N',N'-Tetra-kis(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine]-iron(II) bis-(perchlorate) methanol solvate.

ABSTRACT: In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octa-hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N',N'-tetra-kis-(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol mol-ecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539?(14) and 0.461?(14). N-H?O and C-H?O hydrogen bonds, as well as ?-? stacking inter-actions between the imidazol rings and between the imidazol and benzene rings [centroid-centroid distances = 3.714?(2) and 3.705?(2)?Å] give rise to a three-dimensional network.

SUBMITTER: Wu GL 

PROVIDER: S-EPMC3089232 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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[N,N,N',N'-Tetra-kis(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine]-iron(II) bis-(perchlorate) methanol solvate.

Wu Gui-Ling GL   Ou Chun-Ping CP   Wang Feng F   Zhang Jian-Ming JM   Lan She-Min SM  

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octa-hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N',N'-tetra-kis-(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol mol-ecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14).  ...[more]

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