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[1,2-Bis(pyridin-2-ylmeth-oxy)benzene-?N,O,O',N']dichloridocopper(II).

ABSTRACT: In the title compound, [CuCl(2)(C(18)H(16)N(2)O(2))], the Cu(II) atom lies on a twofold axis and is six-coordinated in a distorted octa-hedral environment defined by two N and two O atoms from the ligand and by two Cl atoms. In the crystal, ?-? inter-actions [centroid-centroid distance = 3.838?(1)?Å] and C-H?Cl hydrogen bonds link adjacent mol-ecules into a chain structure along [101].

SUBMITTER: Huang NN

PROVIDER: S-EPMC3089321 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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[1,2-Bis(pyridin-2-ylmeth-oxy)benzene-κN,O,O',N']dichloridocopper(II).

Huang Nan-Nan NN Zhang Shuang S Liu Ying Y Hou Guang-Feng GF Gao Jin-Sheng JS

Acta crystallographica. Section E, Structure reports online 20110416 Pt 5

In the title compound, [CuCl(2)(C(18)H(16)N(2)O(2))], the Cu(II) atom lies on a twofold axis and is six-coordinated in a distorted octa-hedral environment defined by two N and two O atoms from the ligand and by two Cl atoms. In the crystal, π-π inter-actions [centroid-centroid distance = 3.838 (1) Å] and C-H⋯Cl hydrogen bonds link adjacent mol-ecules into a chain structure along [101]. ...[more]

PMID: 21754316

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