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Di-?-chlorido-bis-{[1,2-bis-(pyridin-2-ylmeth-oxy)benzene-?N,O,O',N']chloridocadmium}.

ABSTRACT: In centrosymmetric dinuclear title compound, [Cd(2)Cl(4)(C(18)H(16)N(2)O(2))(2)], the Cd(II) atom is seven-coordinated in a penta-gonal-bipyramidal environment defined by two N atoms and two O atoms from one ligand and three Cl(-) anions, two of which are bridging. A ?-? inter-action between adjacent pyridine rings [centroid-centroid distance = 3.773?(1)?Å] further stablizes the dimer.

SUBMITTER: Gao JS

PROVIDER: S-EPMC3201405 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-{[1,2-bis-(pyridin-2-ylmeth-oxy)benzene-κN,O,O',N']chloridocadmium}.

Gao Jin-Sheng JS Yu Ying-Hui YH Liu Ying Y Hou Guang-Feng GF

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In centrosymmetric dinuclear title compound, [Cd(2)Cl(4)(C(18)H(16)N(2)O(2))(2)], the Cd(II) atom is seven-coordinated in a penta-gonal-bipyramidal environment defined by two N atoms and two O atoms from one ligand and three Cl(-) anions, two of which are bridging. A π-π inter-action between adjacent pyridine rings [centroid-centroid distance = 3.773 (1) Å] further stablizes the dimer. ...[more]

PMID: 22064381

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