Unknown

Dataset Information

0

Tetraaqua-tetrakis-{?(2)-[1-(carb-oxylato-meth-yl)cyclo-hex-yl]methanaminium}bis(?(3)-hydroxido)bis(nitrato-?O,O')tetrazinc(II).

ABSTRACT: As the title gabapentin complex, [Zn(4)(OH)(2)(NO(3))(2)(C(9)H(17)NO(2))(4)(H(2)O)(4)](NO(3))(4) is located about a centre of inversion, the asymmetric unit contains two disordered nitrate ions and half a complex mol-ecule. The two zinc ions have different coordination environments: one is slightly distorted octa-hedral and the other is trigonal-pyramidal. The conformation of the gabapentin mol-ecule is defined by the formation of two intra-molecular O-H?O hydrogen bonds. Furthermore, the ammonium H atoms are involved in numerous hydrogen bonds with the disordered nitrate anions.

SUBMITTER: de Vries EJ 

PROVIDER: S-EPMC3089351 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tetraaqua-tetrakis-{μ(2)-[1-(carb-oxylato-meth-yl)cyclo-hex-yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κO,O')tetrazinc(II).

de Vries Elise J C EJ   Gamble Caryn C   Shaikjee Ahmed A  

Acta crystallographica. Section E, Structure reports online 20110413 Pt 5

As the title gabapentin complex, [Zn(4)(OH)(2)(NO(3))(2)(C(9)H(17)NO(2))(4)(H(2)O)(4)](NO(3))(4) is located about a centre of inversion, the asymmetric unit contains two disordered nitrate ions and half a complex mol-ecule. The two zinc ions have different coordination environments: one is slightly distorted octa-hedral and the other is trigonal-pyramidal. The conformation of the gabapentin mol-ecule is defined by the formation of two intra-molecular O-H⋯O hydrogen bonds. Furthermore, the ammoni  ...[more]

Similar Datasets

Unknown [1-(Carb-oxy-meth-yl)cyclo-hex-yl]methanaminium nitrate.
| S-EPMC3051645 | biostudies-literature
Unknown Cyclo-hex-yl(meth-yl)ammonium {bis-[cyclo-hex-yl(meth-yl)amino]-phosphor-yl}(4-methyl-phenyl-sulfon-yl)aza-nide.
| S-EPMC3201332 | biostudies-literature
Unknown 5,5-Bis(hydroxy-meth-yl)-3-methyl-cyclo-hex-2-enone.
| S-EPMC2960602 | biostudies-literature
Unknown rac-4-(2-Meth-oxy-phen-yl)-2,6-dimethyl-cyclo-hex-3-ene-carb-oxy-lic acid.
| S-EPMC2979589 | biostudies-literature
Unknown (4-Meth-oxy-phen-yl)(4-methyl-cyclo-hex-yl)methanone.
| S-EPMC3470209 | biostudies-literature
Unknown 1-[4-(Iodo-meth-yl)cyclo-hex-yl]-4-methyl-benzene.
| S-EPMC3120325 | biostudies-literature
Unknown (4-Ethyl-cyclo-hex-yl)(4-meth-oxy-phen-yl)methanone.
| S-EPMC3588434 | biostudies-literature
Unknown (4-Meth-oxy-phen-yl)(4-propyl-cyclo-hex-yl)methanone.
| S-EPMC3588551 | biostudies-literature
Unknown (5-Bromo-2-meth-oxy-phen-yl)(4-ethyl-cyclo-hex-yl)methanone.
| S-EPMC3089268 | biostudies-literature
Unknown 4-[(4-Meth-oxy-benzene-sulfonamido)-meth-yl]cyclo-hexane-1-carb-oxy-lic acid.
| S-EPMC3200917 | biostudies-literature