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Phyllo-poly[[?(2)-1,4-bis-(cyclo-hexyl-sulfanylmeth-yl)benzene-?S:S'](?(2)-nitrato-?O:O')silver(I)].

ABSTRACT: The title compound, [Ag(NO(3))(C(20)H(30)S(2))](n), was synthesized by the reaction of silver nitrate and 1,4-bis-(cyclo-hexyl-thio-meth-yl)benzene (bctmb) in acetonitrile. The coordination polymer exhibits a two-dimensional layer structure. The layers are wave-like and parallel to the crystallographic ac plane; Ag(I) ions are linked by the bctmb ligands and nitrate anions along the crystallographic a and c directions, respectively. In addition, the crystal structure is stabilized by C-H?O hydrogen bonds.

SUBMITTER: Kim TH

PROVIDER: S-EPMC2969017 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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Phyllo-poly[[μ(2)-1,4-bis-(cyclo-hexyl-sulfanylmeth-yl)benzene-κS:S'](μ(2)-nitrato-κO:O')silver(I)].

Kim Tae Ho TH Shin Yong Woon YW Park Ki-Min KM Kim Jineun J

Acta crystallographica. Section E, Structure reports online 20090311 Pt 4

The title compound, [Ag(NO(3))(C(20)H(30)S(2))](n), was synthesized by the reaction of silver nitrate and 1,4-bis-(cyclo-hexyl-thio-meth-yl)benzene (bctmb) in acetonitrile. The coordination polymer exhibits a two-dimensional layer structure. The layers are wave-like and parallel to the crystallographic ac plane; Ag(I) ions are linked by the bctmb ligands and nitrate anions along the crystallographic a and c directions, respectively. In addition, the crystal structure is stabilized by C-H⋯O hydro ...[more]

PMID: 21582336

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