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Bis[(2S,4S)-4-(2-hy-droxy-eth-yl)-2-methyl-piperazine-1,4-diium] di-?-chlorido-bis-[trichloridocadmium(II)].

ABSTRACT: The asymmetric unit of the title compound, (C(7)H(18)N(2)O)(2)[Cd(2)Cl(8)], comprises one 4-(2-hy-droxy-eth-yl)-2-methyl-piperazine-1,4-diium dication and a half [Cd(2)Cl(8)](4-) anion. The two Cd atoms are each coordinated by two bridging Cl atoms and three terminal Cl atoms and the [Cd(2)Cl(8)](4-) anion is located on an inversion centre. The crystal structure consists of N-H?Cl hydrogen-bonded sheets, which are further linked by C-H?Cl contacts, yielding a three-dimensional network.

SUBMITTER: Rong T 

PROVIDER: S-EPMC3099779 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Bis[(2S,4S)-4-(2-hy-droxy-eth-yl)-2-methyl-piperazine-1,4-diium] di-μ-chlorido-bis-[trichloridocadmium(II)].

Rong Tao T  

Acta crystallographica. Section E, Structure reports online 20110302 Pt 4

The asymmetric unit of the title compound, (C(7)H(18)N(2)O)(2)[Cd(2)Cl(8)], comprises one 4-(2-hy-droxy-eth-yl)-2-methyl-piperazine-1,4-diium dication and a half [Cd(2)Cl(8)](4-) anion. The two Cd atoms are each coordinated by two bridging Cl atoms and three terminal Cl atoms and the [Cd(2)Cl(8)](4-) anion is located on an inversion centre. The crystal structure consists of N-H⋯Cl hydrogen-bonded sheets, which are further linked by C-H⋯Cl contacts, yielding a three-dimensional network. ...[more]

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