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Tris(tetra-butyl-ammonium) tris-(nitrato-?O,O')tetra-kis-(thio-cyanato-?N)thorium(IV).

ABSTRACT: The title compound, (C(16)H(36)N)(3)[Th(NCS)(4)(NO(3))(3)], was obtained from the reaction of Th(NO(3))(4)·5H(2)O with (Bu(4)N)(NCS). The Th(IV) atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio-cyanate ions and to three bidentate nitrate ions. The average Th-N and Th-O bond lengths are 2.481?(10) and 2.57?(3)?Å, respectively.

SUBMITTER: Lozano-Rodriguez MJ 

PROVIDER: S-EPMC3100005 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Tris(tetra-butyl-ammonium) tris-(nitrato-κO,O')tetra-kis-(thio-cyanato-κN)thorium(IV).

Lozano-Rodriguez M Janeth MJ   Thuéry Pierre P   Petit Sébastien S   Copping Roy R   Mustre de Leon Jose J   Den Auwer Christophe C  

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

The title compound, (C(16)H(36)N)(3)[Th(NCS)(4)(NO(3))(3)], was obtained from the reaction of Th(NO(3))(4)·5H(2)O with (Bu(4)N)(NCS). The Th(IV) atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio-cyanate ions and to three bidentate nitrate ions. The average Th-N and Th-O bond lengths are 2.481 (10) and 2.57 (3) Å, respectively. ...[more]

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