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Benzyl-aminium perchlorate-18-crown-6 (1/1).


ABSTRACT: In the title compound, C(7)H(10)N(+)·ClO(4) (-)·C(20)H(24)O(6), the proton-ated benzyl-amine cation forms a rotator-stator complex with the 18-crown-6 (1,4,7,10,13,16-hexa-oxacyclo-octa-deca-ne) mol-ecule via N-H?O hydrogen bonds. The cations are associated via weak C-H?? inter-actions, forming chains parallel to [011], while the perclorate anions are located between these chains.

SUBMITTER: Wang WZ 

PROVIDER: S-EPMC3100026 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Benzyl-aminium perchlorate-18-crown-6 (1/1).

Wang Wen-Zhe WZ   Li Xiu-Juan XJ   Wang Na N  

Acta crystallographica. Section E, Structure reports online 20110302 Pt 4


In the title compound, C(7)H(10)N(+)·ClO(4) (-)·C(20)H(24)O(6), the proton-ated benzyl-amine cation forms a rotator-stator complex with the 18-crown-6 (1,4,7,10,13,16-hexa-oxacyclo-octa-deca-ne) mol-ecule via N-H⋯O hydrogen bonds. The cations are associated via weak C-H⋯π inter-actions, forming chains parallel to [011], while the perclorate anions are located between these chains. ...[more]

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