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Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes.

ABSTRACT: A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

SUBMITTER: Miura T 

PROVIDER: S-EPMC3107559 | biostudies-literature | 2011

REPOSITORIES: biostudies-literature

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Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes.

Miura Tomoya T   Biyajima Tsuneaki T   Toyoshima Takeharu T   Murakami Masahiro M  

Beilstein journal of organic chemistry 20110509

A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst. ...[more]

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