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Bis(1-methyl-piperidinium) tetra-chlorido-cuprate(II).

ABSTRACT: The structure of the title compound, (C(6)H(14)N)(2)[CuCl(4)], consists of two inequivalent 1-methyl-piperidinium cations and a flattened tetra-hedral [CuCl(4)](2-) anion. Each organic cation exhibits a chair conformation with the methyl group in the equatorial position. They are segregated into alternating layers parallel to (100) and stacked along [100]. The first cation is arranged in parallel stacks in a herringbone pattern with rows of [CuCl(4)](2-) anions fitting between the stacks and with a Cl(-) ion directed into the inter-ior of the layer. The second organic cation forms distorted hcp layers that separate the other organic cation/[CuCl(4)](2-) slabs. N-H?Cl hydrogen bonding between the cations and the anions consolidates the crystal packing.

SUBMITTER: Reynolds BJ

PROVIDER: S-EPMC3120374 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Bis(1-methyl-piperidinium) tetra-chlorido-cuprate(II).

Reynolds Bryan J BJ Bond Marcus R MR

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The structure of the title compound, (C(6)H(14)N)(2)[CuCl(4)], consists of two inequivalent 1-methyl-piperidinium cations and a flattened tetra-hedral [CuCl(4)](2-) anion. Each organic cation exhibits a chair conformation with the methyl group in the equatorial position. They are segregated into alternating layers parallel to (100) and stacked along [100]. The first cation is arranged in parallel stacks in a herringbone pattern with rows of [CuCl(4)](2-) anions fitting between the stacks and wit ...[more]

PMID: 21754622

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