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Crystal structure of bis-(N,N,N',N'-tetra-methyl-guanidinium) tetra-chlorido-cuprate(II).

ABSTRACT: In the structure of the title salt, (C5H14N3)2[CuCl4], the Cu(II) atom in the anion lies on a twofold rotation axis. The tetra-chlorido-cuprate(II) anion adopts a flattened tetra-hedral coordination environment and inter-acts electrostatically with the tetra-methyl-guanidinium cation. The crystal packing is additionally consolidated through N-H⋯Cl and C-H⋯Cl hydrogen bonds, resulting in a three-dimensional network structure.

SUBMITTER: Ndiaye M

PROVIDER: S-EPMC4992935 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(N,N,N',N'-tetra-methyl-guanidinium) tetra-chlorido-cuprate(II).

Ndiaye Mamadou M Samb Abdoulaye A Diop Libasse L Maris Thierry T

Acta crystallographica. Section E, Crystallographic communications 20160624 Pt 7

In the structure of the title salt, (C5H14N3)2[CuCl4], the Cu(II) atom in the anion lies on a twofold rotation axis. The tetra-chlorido-cuprate(II) anion adopts a flattened tetra-hedral coordination environment and inter-acts electrostatically with the tetra-methyl-guanidinium cation. The crystal packing is additionally consolidated through N-H⋯Cl and C-H⋯Cl hydrogen bonds, resulting in a three-dimensional network structure. ...[more]

PMID: 27555960

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