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Bis{?-2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-?O:O'}bis-(bis-(4-chloro-benz-yl){2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-?O,O'}tin(IV)).

ABSTRACT: The dinuclear title complex, [Sn(2)(C(7)H(6)Cl)(4)(C(9)H(16)NO(2)S(2))(4)], lies on a center of inversion. The Sn(IV) atoms are chelated by one of the two carboxyl-ate ions; the other carboxyl-ate ion bridges two metal atoms. The geometry of the six-coordinate Sn(IV) atom is a distorted trans-C(2)SnO(4) octa-hedron [C-Sn-C = 155.32?(8)°].

SUBMITTER: Keng TC

PROVIDER: S-EPMC3120461 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Bis{μ-2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-κO:O'}bis-(bis-(4-chloro-benz-yl){2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-κO,O'}tin(IV)).

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The dinuclear title complex, [Sn(2)(C(7)H(6)Cl)(4)(C(9)H(16)NO(2)S(2))(4)], lies on a center of inversion. The Sn(IV) atoms are chelated by one of the two carboxyl-ate ions; the other carboxyl-ate ion bridges two metal atoms. The geometry of the six-coordinate Sn(IV) atom is a distorted trans-C(2)SnO(4) octa-hedron [C-Sn-C = 155.32 (8)°]. ...[more]

PMID: 21754573

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