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Poly[hexa-aqua-bis-(?(3)-hepta-nedioato-?O:O':O'')dimagnesium].

ABSTRACT: In the title compound, [Mg(2)(C(7)H(10)O(4))(2)(H(2)O)(6)](n), the Mg(II) ion is coordinated by three aqua ligands and three O atoms from three heptanedioato ligands in a distorted octa-hedral geometry. Each heptanedioato ligand bridges three Mg atoms, generating polymeric layers parallel to the bc plane. The polymeric layers related by translation along the a axis inter-act further via O-H?O hydrogen bonds, which consolidate the crystal packing.

SUBMITTER: Guo XX

PROVIDER: S-EPMC3120615 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Poly[hexa-aqua-bis-(μ(3)-hepta-nedioato-κO:O':O'')dimagnesium].

Guo Xia-Xia XX Lin Jian-Li JL

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title compound, [Mg(2)(C(7)H(10)O(4))(2)(H(2)O)(6)](n), the Mg(II) ion is coordinated by three aqua ligands and three O atoms from three heptanedioato ligands in a distorted octa-hedral geometry. Each heptanedioato ligand bridges three Mg atoms, generating polymeric layers parallel to the bc plane. The polymeric layers related by translation along the a axis inter-act further via O-H⋯O hydrogen bonds, which consolidate the crystal packing. ...[more]

PMID: 21754577

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