Ontology highlight
ABSTRACT:
SUBMITTER: Casey BM
PROVIDER: S-EPMC3145047 | biostudies-literature | 2011 Aug
REPOSITORIES: biostudies-literature
Casey Brian M BM Flowers Robert A RA
Journal of the American Chemical Society 20110708 30
The coupling of enolates through single-electron oxidation is one of the most direct routes for generating 1,4-dicarbonyls. Recent work on the intermolecular heterocoupling of equimolar amounts of two different enolates through single-electron oxidation has shown that synthetically useful yields beyond those predicted by statistics can be obtained. To determine the underlying basis for the selective formation of heterocoupled products, kinetic, (7)Li NMR, and synthetic studies were performed. Th ...[more]