Browse
Submit Data
Databases
API
Help

Dataset Information

21 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-?N)diazen-yl]aniline}zinc.

ABSTRACT: In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen-yl]aniline ligands and two Cl atoms, resulting in a distorted tetra-hedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak inter-molecular C-H?Cl hydrogen bonds and ?-? inter-actions, with centroid-centroid distances of 3.8452?(14) and 3.9932?(14)?Å, are found in the crystal packing.

SUBMITTER: Leesakul N

PROVIDER: S-EPMC3151768 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen-yl]aniline}zinc.

Leesakul Nararak N Pakawatchai Chaveng C Saithong Saowanit S Tantirungrotechai Yuthana Y Kwanplod Kwanchanok K

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen-yl]aniline ligands and two Cl atoms, resulting in a distorted tetra-hedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak inter-molecular C-H⋯Cl hydrogen bonds and π-π inter-actions, with centroid-centroid distances of 3.8452 (14) and 3.9932 (14) Å, are found in the crystal packing. ...[more]

PMID: 21836935

Similar Datasets

N,N-Diethyl-4-[(E)-(pyridin-3-yl)diazen-yl]aniline.

Project description:The mol-ecule of the title compound, C15H18N4, adopts a trans conformation with respect to the diazo N=N bond. The dihedral angle between the benzene and pyridine rings in the mol-ecule is 8.03?(5)°. In the crystal, a weak C-H?? inter-action arranges the mol-ecules into a corrugated ribbon, with an anti-parallel orientation of neighboring mol-ecules propagating in the [100] direction.

| S-EPMC3793775 | biostudies-literature

Crystal structure of 2-[2-(pyridin-3-yl)diazen-1-yl]aniline.

Project description:The crystal structure of the title compound, C11H10N4, comprises mol-ecules in a trans conformation for which all the atoms are located in general positions. The six-membered rings are coplanar and this arrangement might be stabilized by intra-molecular N-H?N hydrogen bonding. In the crystal, the mol-ecules are linked into helical chains parallel to the b axis via N-H?N hydrogen bonding. The mol-ecular packing shows a herringbone-like pattern along the a axis. Comparison of the X-ray powder diffraction with that calculated from single crystal data proves that a pure crystalline phase was obtained and UV-Vis measurements reveal that only the trans isomer is present.

| S-EPMC6038623 | biostudies-literature

4-[(2-Chloro-4-nitro-phen-yl)diazen-yl]-N,N-diethyl-aniline.

Project description:In the title compound, C(16)H(17)ClN(4)O(2), the aromatic ring is twisted slightly with respect to the plane of the diazene group [N-N-C-C torsion angle = -3.9?(4)°]. The NO(2) group is twisted by 16.2?(4)° relative to the aromatic ring. The two ethyl chains are positioned such that one ethyl chain lies above and the other below the ring.

| S-EPMC3052010 | biostudies-literature

Dichloridobis(4-fluoro-aniline-?N)zinc.

Project description:In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra-hedral geometry, being coordinated by the N atoms of two 4-fluoro-aniline mol-ecules and the two Cl(-) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96?(13)°. In the crystal, mol-ecules are linked via pairs of N-H?Cl hydrogen bonds, forming chains propagating along the b axis. These chains are in turn linked via a second pair of N-H?Cl hydrogen bonds, forming a two-dimensional network parallel to the ab plane. The title compound crystallizes in the space group Pca2(1) and exhibits weak second harmonic generation (SHG) properties.

| S-EPMC3435581 | biostudies-literature

N,N-Dimethyl-4-[(2-pyrid-yl)diazen-yl]aniline.

Project description:The title compound, C(13)H(14)N(4), adopts a trans configuration about the azo bond. There is a dihedral angle of 12.18?(7)° between the pyridine and benzene rings and the mean plane of the dimethyl-amino substituent is twisted by 6.1?(2)° relative to the benzene ring. In the crystal, weak inter-molecular C-H?N hydrogen bonds result in a zigzag arrangement along [010].

| S-EPMC3007196 | biostudies-literature

2,4,6-Trinitro-N-[4-(phenyl-diazen-yl)phen-yl]aniline.

Project description:The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl-diazen-yl)aniline (aniline yellow) with picryl-sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl-diazenyl ring system is 6.55?(13)° and that formed by the rings of the picrate-aniline ring system is 48.76?(12)°. The mol-ecule contains an intra-molecular aniline-nitro N-H?O hydrogen bond.

| S-EPMC3099790 | biostudies-literature

4-[(4-Bromo-phen-yl)diazen-yl]-2-eth-oxy-aniline.

Project description:The title compound, C(14)H(14)BrN(3)O, exhibits a trans geometry about the -N=N- double bond. The dihedral angle between the benzene rings is 24.01?(5)°. An intra-molecular N-H?O hydrogen bond occurs. In the crystal, inter-molecular N-H?N hydrogen bonds between the amine groups lead to the formation of a C(8) polymeric chain along [101].

| S-EPMC3239036 | biostudies-literature

4-[(4-Chloro-phen-yl)diazen-yl]-3-meth-oxy-aniline.

Project description:The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20?(8)°. Inter-molecular N-H?O hydrogen bonds between the amine and meth-oxy groups lead to the formation of a chain-like polymer along the c axis with a C(6) graph set. There is also weak non-classical C-H?N hydrogen bonds involving an aromatic C-H group and a diazenyl N atom, which connect the chains into a two-dimensional framework.

| S-EPMC3152038 | biostudies-literature

N,N-Diethyl-4-[1-phenyl-3-(pyridin-2-yl)-4,5-di-hydro-1H-pyrazol-5-yl]aniline.

Project description:In the title mol-ecule, C24H26N4, the pyrazoline ring assumes an envelope conformation with the aniline-bearing C atom at the flap position. The benzene ring and the pyridine ring form with the pyrazoline ring dihedral angles of 4.53?(1) and 6.26?(1)°, respectively. In turn, the aniline group is nearly perpendicular to the pyrazoline ring [dihedral angle = 79.96?(1)°]. The ethyl groups of the di-ethyl-amine substituent are disordered over two sets of sites, with an occupancy ratio of 0.624?(8):0.376?(8).

| S-EPMC3793803 | biostudies-other

2-[(2,6-Diethyl-phen-yl)imino-meth-yl]-N-(2-methoxy-phen-yl)aniline.

Project description:The title anilide-imine compound, C(24)H(26)N(2)O, features an intra-molecular N-H?N hydrogen bond involving the imine and anilide groups to generate an S(6) ring motif. The mol-ecule displays an E configuration about the imine C=N double bond, with the dihedral angle between the two benzene rings being 86.5°. The packing is stabilized by three different C-H?? inter-actions.

| S-EPMC2970353 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data