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Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-?N)diazen-yl]aniline}zinc.

ABSTRACT: In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen-yl]aniline ligands and two Cl atoms, resulting in a distorted tetra-hedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak inter-molecular C-H?Cl hydrogen bonds and ?-? inter-actions, with centroid-centroid distances of 3.8452?(14) and 3.9932?(14)?Å, are found in the crystal packing.

SUBMITTER: Leesakul N

PROVIDER: S-EPMC3151768 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen-yl]aniline}zinc.

Leesakul Nararak N Pakawatchai Chaveng C Saithong Saowanit S Tantirungrotechai Yuthana Y Kwanplod Kwanchanok K

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen-yl]aniline ligands and two Cl atoms, resulting in a distorted tetra-hedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak inter-molecular C-H⋯Cl hydrogen bonds and π-π inter-actions, with centroid-centroid distances of 3.8452 (14) and 3.9932 (14) Å, are found in the crystal packing. ...[more]

PMID: 21836935

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