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Dichloridobis(isoquinoline-?N)zinc(II).


ABSTRACT: In the title compound, [ZnCl(2)(C(9)H(7)N)(2)], the Zn(II) cation is coordinated by two Cl(-) anions and two isoquinoline ligands in a distorted ZnCl(2)N(2) tetra-hedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72?(8)°. The parallel isoqiunoline ring systems of adjacent mol-ecules are partially overlapped, with the shorter face-to-face distance of 3.438?(19)?Å indicating the existence of weak ?-? stacking in the crystal structure.

SUBMITTER: Li MJ 

PROVIDER: S-EPMC3007211 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Dichloridobis(isoquinoline-κN)zinc(II).

Li Meng-Jiao MJ   Nie Jing-Jing JJ   Xu Duan-Jun DJ  

Acta crystallographica. Section E, Structure reports online 20100703 Pt 8


In the title compound, [ZnCl(2)(C(9)H(7)N)(2)], the Zn(II) cation is coordinated by two Cl(-) anions and two isoquinoline ligands in a distorted ZnCl(2)N(2) tetra-hedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)°. The parallel isoqiunoline ring systems of adjacent mol-ecules are partially overlapped, with the shorter face-to-face distance of 3.438 (19) Å indicating the existence of weak π-π stacking in the crystal structur  ...[more]

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