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Dichlorido(4-meth-oxy-2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenol-ate)cadmium.


ABSTRACT: In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol-ecules are linked through C-H?? inter-actions into infinite chains along the a axis. The mol-ecules are further connected into a three-dimensional network via N-H?O, N-H?Cl and C-H?Cl inter-actions. The ethyl-ene group is disordered over two sets of sites in a 0.520?(10):0.480?(10) ratio.

SUBMITTER: Saleh Salga M 

PROVIDER: S-EPMC3151769 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Dichlorido(4-meth-oxy-2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenol-ate)cadmium.

Saleh Salga Muhammad M   Khaledi Hamid H   Mohd Ali Hapipah H  

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7


In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol-ecules are linked through C-H⋯π inter-actions into infinite chains along the a axis. The mol-ecules are further connected into a three-dimensional network via N-H⋯O, N-H⋯Cl and C-H⋯Cl inter-actions. The ethyl-ene group is disordered over t  ...[more]

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