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Catena-Poly[[bis-(nitrato-?O)copper(II)]-?-1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)-benzene-?N:N'].


ABSTRACT: In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric chain running along the [101] direction. The three O atoms of the nitrate group are disordered over two positions in a 3:2 ratio.

SUBMITTER: Wang PN 

PROVIDER: S-EPMC3152049 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(nitrato-κO)copper(II)]-μ-1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)-benzene-κN:N'].

Wang Pin-Ning PN   Yeh Chun-Wei CW   Tsai Hui-An HA   Wang Ju-Chun JC   Suen Maw-Cherng MC  

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7


In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric chain running along the [101] direction. The three O atoms of the nitrate group are disordered over tw  ...[more]

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