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Tetra-kis[?-1,3-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene-?(2)N:N']tris-ilver(I) tris-(hexa-fluoridophosphate).

ABSTRACT: In the title compound, [Ag(3)(C(12)H(12)N(2)O(2))(4)](PF(6))(3), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetra-hedral geometry and the other Ag(I) ion is coordinated by two N atoms from two L ligands in a bent arrangement [N-Ag-N = 169.03?(17)°]. Two L ligands adopt a syn conformation, while the other two adopt an anti conformation. They bridge adjacent Ag(I) ions, forming a trinuclear complex. One of the PF(6) (-) anions is half-occupied, with the P atom located on a twofold rotation axis. The PF(6) (-) anions link the complex mol-ecules via Ag?F inter-actions [2.80?(2) and 2.85?(2)?Å] into a polymeric chain along [100].

SUBMITTER: Yeh CW 

PROVIDER: S-EPMC3435593 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Tetra-kis[μ-1,3-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)N:N']tris-ilver(I) tris-(hexa-fluoridophosphate).

Yeh Chun-Wei CW   Ho Yuh-Wen YW   Lee Hsun-Tsing HT   Wang Ju-Chun JC   Suen Maw-Cherng MC  

Acta crystallographica. Section E, Structure reports online 20120811 Pt 9

In the title compound, [Ag(3)(C(12)H(12)N(2)O(2))(4)](PF(6))(3), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetra-hedral geometry and the other Ag(I) ion is coordinated by two N atoms from two L ligands in a bent arrangement [N-Ag-N = 169.03 (17)°]. Two L ligands adopt a syn conformation, while the other two adopt an anti conformation. They bridge adjacent Ag(I) ions, forming a  ...[more]

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