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Bis{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth-yl]-1H-benzotriazole}bis-(iodido-cadmium).

ABSTRACT: The dinuclear title complex, [Cd(2)I(4)(C(12)H(13)N(5))(2)], lies on a crystallographic center of inversion. The Cd(II) atom is four-coordinated by two N atoms from two 1-[(2-ethyl-1H-imidazol-1-yl)meth-yl]-1H-benzotriazole (bmei) ligands and two terminal I atoms in a distorted tetra-hedral coordination environment. The Cd(II) atoms are connected to each other by two bridging bmei ligands. The benzotriazole rings in adjacent mol-ecules are almost parallel, with an average inter-planar distance of 3.3400 (2) Å and a centroid-centroid distance of 4.852 (2) Å.

SUBMITTER: Wang X

PROVIDER: S-EPMC3152091 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Bis{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth-yl]-1H-benzotriazole}bis-(iodido-cadmium).

Wang Xia X Niu Jun-Long JL

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

The dinuclear title complex, [Cd(2)I(4)(C(12)H(13)N(5))(2)], lies on a crystallographic center of inversion. The Cd(II) atom is four-coordinated by two N atoms from two 1-[(2-ethyl-1H-imidazol-1-yl)meth-yl]-1H-benzotriazole (bmei) ligands and two terminal I atoms in a distorted tetra-hedral coordination environment. The Cd(II) atoms are connected to each other by two bridging bmei ligands. The benzotriazole rings in adjacent mol-ecules are almost parallel, with an average inter-planar distance o ...[more]

PMID: 21836875

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