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Poly[bis-(?(2)-5-{4-[(1H-imidazol-1-yl)meth-yl]phen-yl}tetra-zolato)zinc].

ABSTRACT: In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth-yl)phen-yl]tetra-zolate ligands in a distorted tetra-hedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C-H?N, C-H?? and ?-? [centroid-centroid distance = 3.7523?(11)?Å] inter-actions within the network.

SUBMITTER: Song Z

PROVIDER: S-EPMC3569184 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Poly[bis-(μ(2)-5-{4-[(1H-imidazol-1-yl)meth-yl]phen-yl}tetra-zolato)zinc].

Song Zhe Z

Acta crystallographica. Section E, Structure reports online 20130109 Pt 2

In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth-yl)phen-yl]tetra-zolate ligands in a distorted tetra-hedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C-H⋯N, C-H⋯π and π-π [centroid-centroid distance = 3.7523 (11) Å] inter-actions within the network. ...[more]

PMID: 23424428

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