Unknown

Dataset Information

0

Catena-Poly[[bis-(1-ethyl-1H-imidazole-?N)cadmium]-di-?-chlorido-[(1-ethyl-1H-imidazole-?N)cadmium]-di-?-chlorido-[(1-ethyl-1H-imidazole-?N)cadmium]-di-?-chlorido-[bis-(1-ethyl-1H-imidazole-?N)cadmium]].

ABSTRACT: The asymmetric unit of the crystal structure of the title compound, [Cd(2)Cl(4)(C(5)H(8)N(2))(3)](n), contains two Cd(II) cations, three 1-ethyl-1H-imidazole ligands, and four Cl(-) anions. The two Cd(II) atoms have quite different coordination environments: one is octa-hedrally coordinated by four Cl atoms and two N atoms from two 1-ethyl-1H-imidazole ligands, and the second is in a severely distorted fivefold coordination by four Cl atoms and one N atom from a 1-ethyl-1H-imidazole ligand. Adjacent Cd(II) cations are inter-connected alternately by pairs of chloride bridges, generating an infinite step-like chain along the a axis. One ethyl group of the 1-ethyl-1H-imidazole ligand is disordered over two sets of sites with a 0.668?(13):0.332?(13) site-occupancy ratio.

SUBMITTER: Xu Q 

PROVIDER: S-EPMC3238745 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[bis-(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN)cadmium]-di-μ-chlorido-[bis-(1-ethyl-1H-imidazole-κN)cadmium]].

Xu Qian Q   Zhu Run-Qiang RQ  

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

The asymmetric unit of the crystal structure of the title compound, [Cd(2)Cl(4)(C(5)H(8)N(2))(3)](n), contains two Cd(II) cations, three 1-ethyl-1H-imidazole ligands, and four Cl(-) anions. The two Cd(II) atoms have quite different coordination environments: one is octa-hedrally coordinated by four Cl atoms and two N atoms from two 1-ethyl-1H-imidazole ligands, and the second is in a severely distorted fivefold coordination by four Cl atoms and one N atom from a 1-ethyl-1H-imidazole ligand. Adja  ...[more]

Similar Datasets

Unknown catena-Poly[(dichloridocadmium)-di-?-chlorido-[bis-(morpholinium-?O)cadmium]-di-?-chlorido].
| S-EPMC3212201 | biostudies-literature
Unknown catena-Poly[di-μ3-bromido-bis-[(1-ethyl-1H-imidazole-κN (3))disilver(I)]].
| S-EPMC3772437 | biostudies-literature
Unknown catena-Poly[[diaqua-bis-(2-ethyl-1H-imidazole-?N(3))cadmium]-?-sulfato-?(2)O:O'].
| S-EPMC3344375 | biostudies-literature
Unknown catena-Poly[cadmium-?-[1,3-bis-(imidazol-1-yl)propane]-di-?-chlorido].
| S-EPMC3379108 | biostudies-literature
Unknown catena-Poly[[bis[quinazolin-4(3H)-one-?N]cadmium(II)]-di-?-chlorido].
| S-EPMC3009324 | biostudies-literature
Unknown catena-Poly[[bis-[1-(2-hydroxy-ethyl)-1H-tetra-zole-κN]copper(II)]-di-μ-chlorido]: a powder study.
| S-EPMC2961963 | biostudies-literature
Unknown catena-Poly[[chloridocadmium(II)]bis-{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth-yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido].
| S-EPMC3151992 | biostudies-literature
Unknown catena-Poly[[bis-(1-ethyl-1H-imidazole-κN)copper(II)]-μ-oxalato-κO,O:O,O].
| S-EPMC3246998 | biostudies-literature
Unknown catena-Poly[[[aqua-chlorido-manganese(II)]-bis-[μ-1,1'-(oxydi-p-phenyl-ene)di-1H-imidazole-κN:N]] chloride dimethyl-formamide mono-solvate monohydrate].
| S-EPMC3051568 | biostudies-literature
Unknown Di-μ-chlorido-bis-(chlorido-{8-[2-(di-methyl-amino)-ethyl-amino]-quinoline}-cadmium) ethanol monosolvate.
| S-EPMC9462312 | biostudies-literature