Unknown

Dataset Information

0

1,1'-[(5-Hy-droxy-methyl-1,3-phenyl-ene)bis-(methyl-ene)]dipyridin-4(1H)-one monohydrate.

ABSTRACT: The asymmetric unit of the title compound, C(19)H(18)N(2)O(3), comprises a whole organic dipyridinone mol-ecule plus a water mol-ecule of crystallization. The planes of the pyridinone rings are approximately perpendicular with the plane of the central aromatic ring [dihedral angles = 80.68?(8) and 83.65?(8)°]. The C-O bond of the hy-droxy group subtends an angle of 31.71?(10)° with the plane through the central aromatic ring. The crystal packing is mediated by the presence of several O-H?O hydrogen-bonding inter-actions and while the water mol-ecules form a C(2) (1)(4) chain parallel to the c axis of the unit cell, the pendant hy-droxy groups are engaged in O-H?O=C hydrogen bonds described by a C(1) (1)(12) graph-set motif which runs parallel to the a axis.

SUBMITTER: Fernandes JA 

PROVIDER: S-EPMC3152136 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

1,1'-[(5-Hy-droxy-methyl-1,3-phenyl-ene)bis-(methyl-ene)]dipyridin-4(1H)-one monohydrate.

Fernandes José A JA   Lago Manuela E L ME   Silva Sandrina S   Tomé João P C JP   Cavaleiro José A S JA   Almeida Paz Filipe A FA  

Acta crystallographica. Section E, Structure reports online 20110630 Pt 7

The asymmetric unit of the title compound, C(19)H(18)N(2)O(3), comprises a whole organic dipyridinone mol-ecule plus a water mol-ecule of crystallization. The planes of the pyridinone rings are approximately perpendicular with the plane of the central aromatic ring [dihedral angles = 80.68 (8) and 83.65 (8)°]. The C-O bond of the hy-droxy group subtends an angle of 31.71 (10)° with the plane through the central aromatic ring. The crystal packing is mediated by the presence of several O-H⋯O hydro  ...[more]

Similar Datasets

Unknown 1,1'-[(2-Phenyl-2,3-dihydro-1H-benz-imidazole-1,3-di-yl)bis-(methyl-ene)]bis-(1H-benzotriazole).
| S-EPMC3274994 | biostudies-literature
Unknown 1,1'-[Imidazolidine-1,3-diylbis(methyl-ene)]bis-(1H-benzotriazole).
| S-EPMC3275003 | biostudies-literature
Unknown 1,1'-[(2,3,3a,4,5,6,7,7a-Octa-hydro-1H-1,3-benzimidazole-1,3-di-yl)bis-(methyl-ene)]bis-(1H-benzotriazole).
| S-EPMC3247461 | biostudies-literature
Unknown 1,1'-[2,3,5,6-Tetra-methyl-p-phenyl-ene-bis(methyl-eneoxy)]di-1H-benzotriazole.
| S-EPMC2969066 | biostudies-literature
Unknown Chlorido[1,1'-(5-methyl-1,3-phenyl-ene)bis-(3,5-dimethyl-1H-imidazol-2-yl-idene)]platinum(II).
| S-EPMC3629494 | biostudies-literature
Unknown 1,1'-[1,4-Phenyl-enebis(methyl-ene)]bis-(2-methyl-1H-imidazol-3-ium) 2,4-dicarb-oxy-benzene-1,5-dicarboxyl-ate monohydrate.
| S-EPMC3151773 | biostudies-literature
Unknown 1,1'-{2,2'-[1,4-Phenyl-enebis(methyl-ene)]bis-(-oxy)bis-(2,1-phenyl-ene)}diethanone.
| S-EPMC3247415 | biostudies-literature
Unknown Tetra-kis[diamminesilver(I)] bis-(2-hy-droxy-5-methyl-benzene-1,3-disulfonate) monohydrate.
| S-EPMC3238693 | biostudies-literature
Unknown 3,3'-Di-n-propyl-1,1'-(1,3-phenyl-ene-dimethyl-ene)di(1H-imidazol-3-ium) bis-(hexa-fluorophosphate).
| S-EPMC3393961 | biostudies-literature
Unknown 2,2'-{[2-(2-Hy-droxy-phen-yl)-4-methyl-imidazolidine-1,3-di-yl]bis-(methyl-ene)}diphenol.
| S-EPMC3793786 | biostudies-literature