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Metal-free chlorodeboronation of organotrifluoroborates.

ABSTRACT: A mild and metal-free method for the chlorodeboronation of organotrifluoroborates using trichloroisocyanuric acid (TCICA) was developed. Aryl-, heteroaryl-, alkenyl-, alkynyl-, and alkyltrifluoroborates were converted into the corresponding chlorinated products in good yields. This method proved to be tolerant of a broad range of functional groups.

SUBMITTER: Molander GA

PROVIDER: S-EPMC3162988 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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Metal-free chlorodeboronation of organotrifluoroborates.

Molander Gary A GA Cavalcanti Livia N LN

The Journal of organic chemistry 20110803 17

A mild and metal-free method for the chlorodeboronation of organotrifluoroborates using trichloroisocyanuric acid (TCICA) was developed. Aryl-, heteroaryl-, alkenyl-, alkynyl-, and alkyltrifluoroborates were converted into the corresponding chlorinated products in good yields. This method proved to be tolerant of a broad range of functional groups. ...[more]

PMID: 21812468

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