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Poly[[[μ(3)-5-(pyridine-4-carboxamido)-isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl-amino]-isophthalato}-neodymium(III)] dihydrate].

ABSTRACT: In the title compound, {[Nd(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))]·2H(2)O}(n), the Nd(III) atom is eight-coordinated as it is surrounded by eight carboxyl-ate O atoms from six ligands in a distorted square-anti-prismatic arrangement. The Nd(III) atoms are linked by HL(-) and L(2-) ligands [H(2)L is 5-(pyridine-4-carboxamido)-isophthalic acid], forming a bilayer network. The layers are linked into a three-demensional network through N-H⋯O and O-H⋯O hydrogen bonds.

SUBMITTER: Deng YF

PROVIDER: S-EPMC3200962 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Poly[[tetra-aqua-tetra-kis-[μ(3)-5-(pyridine-4-carboxamido)-isophthalato]cobalt(II)dierbium(III)] tetra-hydrate].

Project description:In the centrosymmetric polymeric title compound, {[CoEr(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Er(III) cation has a coordination number of eight and is surrounded by seven carboxyl-ate O atoms from four 5-(pyridine-4-carboxamido)-isophthalate (L) ligands and one water mol-ecule, forming a distorted square-anti-prismatic arrangement. The Co(II) cation is located on an inversion center and is coordinated by two pyridine N atoms, two carboxyl-ate O atoms and two water mol-ecules in a distorted octa-hedral geometry. The asymmetric unit contains two anionic L ligands. One bridges two Er(III) cations and one Co(II) cation through two carboxyl-ate groups and one pyridine N atom, while the other bridges two Er(III) cations and one Co(II) cation through two carboxyl-ate groups. Extensive O-H⋯O, O-H⋯N and N-H⋯O hydrogen-bonding inter-actions are present in the crystal, involving all uncoordinated water mol-ecules and the uncoordinated pyridine N atom of one of the ligands bonded to an adjacent coordinated water mol-ecule. The title compound is isotypic with the gadolinium analogue.

| S-EPMC3246915 | biostudies-literature

Poly[[tetra-aqua-tetra-kis-[μ(3)-5-(pyridine-4-carboxamido)-isophthalato]-cobalt(II)-diholmium(III)] tetra-hydrate].

Project description:In the centrosymmetric polymeric title compound, {[CoHo(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Ho(III) ion is coordinated by one water mol-ecule and four 5-(pyridine-4-carboxamido)-isophthalate (L) ligands in a distorted square-anti-prismatic arrangement. The Co(II) ion, located on an inversion center, is coordinated by two pyridine N atoms, two carboxyl-ate O atoms and two water mol-ecules in a distorted octa-hedral geometry. One L ligand bridges two Ho ions and one Co ion through two carboxyl-ate groups and one pyridine N atom. The other L ligand bridges two Ho ions and one Co ion through two carboxyl-ate groups, while the uncoordinated pyridine N atom accepts a hydrogen bond from an adjacent coordinated water mol-ecule. Extensive O-H⋯O, N-H⋯O and O-H⋯N hydrogen bonding is present in the crystal.

| S-EPMC3246991 | biostudies-literature

Poly[[aqua-[μ(5)-5-(isonicotinamido)-isophthalato][μ(4)-5-(isonicotinamido)-isophthalato]holmium(III)silver(I)] dihydrate].

Project description:The title heteronuclear complex, {[AgHo(C(14)H(8)N(2)O(5))(2)(H(2)O)]·2H(2)O}(n), has a three-dimensional polymeric structure, generated by the carboxyl-ate and pyridine groups of the 5-(isonicotinamido)-isophthalate (INAIP) ligands bridging the metal atoms. The Ho(III) atom is coordinated by seven O atoms from INAIP ligands and a water mol-ecule in a distorted square-anti-prismatic geometry, while the Ag(I) atom has a distorted trigonal-planar AgN(2)O geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds stabilize the crystal structure.

| S-EPMC3393244 | biostudies-literature

Poly[[(μ(4)-5-amino-isophthalato)aqua-iron(II)] dihydrate].

Project description:In the title three-dimensional coordination polymer, {[Fe(C(8)H(5)NO(4))(H(2)O)]·2H(2)O}(n), the Fe(II) atom exhibits a distorted octa-hedral geometry, being coordinated by one N and four O atoms from four 5-amino-isophthalate ligands and one water mol-ecule. In addition, the crystal structure is stabilized by numerous O-H⋯O and N-H⋯O hydrogen bonds.

| S-EPMC2960919 | biostudies-literature

Poly[[tetra-aquatetrakis-[?(3)-5-(pyridine-4-carboxamido)-isophthalato]cobalt(II)digadolinium(III)] tetra-hydrate].

Project description:In the centrosymmetric polymeric title compound, {[CoGd(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Gd(III) cation is coordinated by one water mol-ecule and four pyridine-4-carboxamido-isophthalate (L) anions in a distorted square-anti-prismatic arrangement, while the Co(II) cation, located on an inversion center, is coordinated by two pyridyl-N atoms, two carboxyl-ate-O atoms and two water mol-ecules in a distorted octa-hedral geometry. The asymmetric unit contains two anionic L ligands: one bridges two Gd cations and one Co cation through two carboxyl groups and one pyridine-N atom; the other bridges two Gd cations and one Co cation through two carboxyl groups and the uncoordinated pyridine-N atom is hydrogen-bonded to the adjacent coordinated water mol-ecule. Extensive O-H?O and N-H?O hydrogen bonds are present in the crystal structure.

| S-EPMC3201412 | biostudies-literature

Poly[[diaqua-[?(2)-3-carb-oxy-5-(pyridine-4-carboxamido)-benzoato][?(4)-5-(pyridine-4-carboxamido)-isophthalato]cerium(III)] monohydrate].

Project description:In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not deprotonated and links with the adjacent pyridine ring via an O-H?N hydrogen bond. The Ce(III) cation is coordinated by six O atoms from carboxyl groups and two O atoms from coordinated water mol-ecules in a distorted square-anti-prismatic arrangement. Extensive O-H?O and O-H?N hydrogen bonding occurs in the crystal structure.

| S-EPMC3344292 | biostudies-other

Poly[[tetra-aqua-tetra-kis-[?3-5-(pyridine-4-carboxamido)-isophthalato]nickel(II)diterbium(III)] tetra-hydrate].

Project description:In the title compound, {[NiTb2(C14H8N2O5)4(H2O)4]·4H2O} n , the Tb(III) ion is coordinated by one water mol-ecule and seven O atoms from four 5-(pyridine-4-carboxamido)-isophthalate (L) ligands in a distorted square-anti-prismatic arrangement, while the Ni(II) ion, lying on an inversion center, is six-coordinated in an octa-hedral geometry by two pyridine N atoms, two carboxyl-ate O atoms and two water mol-ecules. One L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxyl-ate groups and one pyridine N atom. The other L ligand bridges two Tb(III) ions and one Ni(II) ion through two carboxyl-ate groups, while the uncoordinating pyridine N atom is hydrogen bonded to an adjacent coordinating water mol-ecule. Extensive O-H?O, N-H?O and O-H?N hydrogen bonds play an important role in stabilizing the crystal structure.

| S-EPMC3772404 | biostudies-literature

Poly[piperazinediium [aqua-bis(μ-pyridine-2,5-dicarboxyl-ato)zincate] dihydrate].

Project description:The polymeric title compound, {(C(4)H(12)N(2))[Zn(C(7)H(3)NO(4))(2)(H(2)O)]·2H(2)O}(n), was obtained by the reaction of zinc(II) nitrate hexa-hydrate with the proton-transfer compound (pipzH(2))(py-2,5-dc) (where pipz is piperazine and py-2,5-dcH(2) is pyridine-2,5-dicarboxylic acid) in aqueous solution. Each Zn(II) atom is coordinated in a distorted octa-hedral geometry by four O atoms and two N atoms from one water mol-ecule and two (py-2,5-dc)(2-) ligands, which also act as bridging ligands between Zn(II) atoms. π-π Stacking inter-actions between two aromatic rings of (py-2,5-dc)(2-) fragments, with centroid-centroid distances of 3.4747 (7) and 3.7081 (7) Å are observed. The crystal structure is stabilized by O-H⋯O and N-H⋯O hydrogen bonds.

| S-EPMC2915064 | biostudies-literature

Poly[[tetra-aqua-bis-(μ(3)-pyridine-2,6-dicarboxyl-ato)(μ(2)-pyridine-2,6-dicarboxyl-ato)dilanthanum(III)] dihydrate].

Project description:There are two independent La(III) cations in the polymeric title compound, {[La(2)(C(7)H(3)NO(4))(3)(H(2)O)(4)]·2H(2)O}(n). One is nine-coordinated in an LaN(2)O(7) tricapped trigonal-prismatic geometry formed by three pyridine-2,6-dicarboxyl-ate anions and two water mol-ecules, while the other is ten-coordinated in an LaNO(9) bicapped square-anti-prismatic geometry formed by four pyridine-2,6-dicarboxyl-ate anions and two water mol-ecules. The two La(III) cations are separated by a non-bonding distance of 5.026 (3) Å. The pyridine-2,6-dicarboxyl-ate anions bridge the La(III) cations, forming a three-dimensional polymeric complex. The crystal structure contains extensive classical O-H⋯O hydrogen bonds and weak inter-molecular C-H⋯O hydrogen bonds. The crystal structure is further consolidated by π-π stacking between pyridine rings, the shortest centroid-centroid distance between parallel pyridine rings being 3.700 (5) Å.

| S-EPMC3200968 | biostudies-literature

catena-Poly[[[diaqua-thulium(III)]-μ-6-carboxy-nicotinato-μ-pyridine-2,5-di-carboxyl-ato] dihydrate].

Project description:The title compound, {[Tm(C(7)H(3)NO(4))(C(7)H(4)NO(4))(H(2)O)(2)]·2H(2)O}(n), is isotypic with the analogous Tb(III) compound [Li et al. (2009 ▶). Acta Cryst. E65, m410]. All interatomic distances and angles and the hydrogen-bond geometries are very similar for the two structures. The refined Flack parameter of 0.49 (2) suggests inversion twinning.

| S-EPMC2968913 | biostudies-literature

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