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N-Diphenyl-phosphanyl-N-{[diphen-yl(2-pyridyl-imino)-?-phosphan-yl]meth-yl}pyridin-2-amine.

ABSTRACT: In the title compound, C(35)H(30)N(4)P(2), the diphenyl-phosphanyl and diphen-yl(2-pyridyl-imino)-?(5)-phosphanyl groups are attached to the central methyl C atom with a P-C-N angle of 114.09?(16)°. The mol-ecules stack along the b axis and inter-connect through C-H(pyrid-yl)?N(pyrid-yl) inter-actions, forming an infinite chain structure. The parallel chains are further inter-connected via C-H(benzene)?N(amino) and C-H(benzene)?? inter-actions, forming a three-dimensional framework.

SUBMITTER: Peng X

PROVIDER: S-EPMC3201310 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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N-Diphenyl-phosphanyl-N-{[diphen-yl(2-pyridyl-imino)-λ-phosphan-yl]meth-yl}pyridin-2-amine.

Peng Xiao X Yuan Yan Y Chen Xue X

Acta crystallographica. Section E, Structure reports online 20110917 Pt 10

In the title compound, C(35)H(30)N(4)P(2), the diphenyl-phosphanyl and diphen-yl(2-pyridyl-imino)-λ(5)-phosphanyl groups are attached to the central methyl C atom with a P-C-N angle of 114.09 (16)°. The mol-ecules stack along the b axis and inter-connect through C-H(pyrid-yl)⋯N(pyrid-yl) inter-actions, forming an infinite chain structure. The parallel chains are further inter-connected via C-H(benzene)⋯N(amino) and C-H(benzene)⋯π inter-actions, forming a three-dimensional framework. ...[more]

PMID: 22058786

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