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N,N-Bis(diphenyl-phosphan-yl)benzyl-amine.

ABSTRACT: In the title compound, C(31)H(27)NP(2), the diphenyl-phosphanyl groups are staggered relative to the PNP backbone. The N atom is displaced by 0.219?(2)?Å from the plane formed by the two P atoms and the methylene C atom. The angles around the N atom are 120.84?(16), 113.29?(16) and 120.57?(12)°, indicating that it exhibits a distorted trigonal-pyramidal geometry. There are no classical inter-molecular inter-actions.

SUBMITTER: Liu XF

PROVIDER: S-EPMC3051494 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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N,N-Bis(diphenyl-phosphan-yl)benzyl-amine.

Liu Xu-Feng XF Xu Wei-Hong WH Li Hui H

Acta crystallographica. Section E, Structure reports online 20110112 Pt 2

In the title compound, C(31)H(27)NP(2), the diphenyl-phosphanyl groups are staggered relative to the PNP backbone. The N atom is displaced by 0.219 (2) Å from the plane formed by the two P atoms and the methylene C atom. The angles around the N atom are 120.84 (16), 113.29 (16) and 120.57 (12)°, indicating that it exhibits a distorted trigonal-pyramidal geometry. There are no classical inter-molecular inter-actions. ...[more]

PMID: 21523048

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