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Catena-Poly[[trans-bis-(cyclo-hexane-1,2-diamine-?²N,N)cadmium]-?-iodido-(diiodidocadmium)-?-iodido].

ABSTRACT: In the title compound, [Cd?I?(C?H??N?)?](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octa-hedral coordination environment by four N atoms from two cyclo-hexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordinated by four iodido ligands in a slightly distorted tetra-hedral coordination environment. Two of the iodido ligands act as bridging ligands connecting Cd(II) ions and forming a one-dimensional polymer along [010]. In the crystal, N-H?I hydrogen bonds connect the one-dimensional structure into a two-dimensional framework parallel to (001).

SUBMITTER: Cui SF

PROVIDER: S-EPMC3393164 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[trans-bis-(cyclo-hexane-1,2-diamine-κ²N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido].

Cui Sheng-Feng SF Wen Qin-Mei QM Zhou Cheng-He CH

Acta crystallographica. Section E, Structure reports online 20120613 Pt 7

In the title compound, [Cd₂I₄(C₆H₁₄N₂)₂](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octa-hedral coordination environment by four N atoms from two cyclo-hexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordinated by four iodido ligands in a slightly distorted tetra-hedral coordination environment. Two of the iodido ligands act as bridging ligands connecting Cd(II) ions and forming a one-dimensional polymer along [010 ...[more]

PMID: 22807732

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