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[4-Bromo-N-(pyridin-2-yl-methyl-idene)aniline-?(2)N,N']iodido(triphenyl-phosphane-?P)copper(I).

ABSTRACT: In the title compound, [CuI(C(12)H(9)BrN(2))(C(18)H(15)P)], the Cu(I) ion is bonded to one I atom, one triphenyl-phosphane P atom and two N atoms of the diimine ligand in a distorted tetra-hedral geometry. The Schiff base acts as a chelating ligand and coordinates to the Cu(I) atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromo-phenyl rings is 19.2?(2)°. In the crystal, mol-ecules are connected by ?-? stacking inter-actions between inversion-related pyridine rings [centroid-centroid distance = 3.404?(3)?Å].

SUBMITTER: Khalaji AD 

PROVIDER: S-EPMC3393242 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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[4-Bromo-N-(pyridin-2-yl-methyl-idene)aniline-κ(2)N,N']iodido(triphenyl-phosphane-κP)copper(I).

Khalaji Aliakbar Dehno AD   Bahramian Bahram B   Jafari Khadijeh K   Fejfarová Karla K   Dušek Michal M  

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the title compound, [CuI(C(12)H(9)BrN(2))(C(18)H(15)P)], the Cu(I) ion is bonded to one I atom, one triphenyl-phosphane P atom and two N atoms of the diimine ligand in a distorted tetra-hedral geometry. The Schiff base acts as a chelating ligand and coordinates to the Cu(I) atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromo-phenyl rings is 19.2 (2)°. In the crystal, mol-ecules are connected by π-π stacking inter-actions between inversion-related pyr  ...[more]

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