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(4-Methyl-benzohydrazidato-κN',O)[2-(4-methyl-benzoyl-hydrazinyl-idene-κN,O)-3-phenyl-propionato(2-)]oxido-vanadium(V) methanol monosolvate.

ABSTRACT: The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazono)propionate dianion. The octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds, generating a centrosymmetric aggregate.

SUBMITTER: Wong HW

PROVIDER: S-EPMC2983918 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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(4-Methyl-benzohydrazidato-κN',O)[2-(4-methyl-benzoyl-hydrazinyl-idene-κN,O)-3-phenyl-propionato(2-)]oxido-vanadium(V) methanol monosolvate.

Wong Hon Wee HW Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100331 Pt 4

The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazono)propionate dianion. The octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds, generating a centrosymmetric aggregate. ...[more]

PMID: 21580561

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(Benzohydrazidato-κN',O)-[2-(benzoyl-hydrazono-κN,O)propion-ato-κO]oxido-vanadium(V).

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