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(E)-N-(Ferrocenyl-methyl-idene)(pyridin-3-yl)methanamine.

ABSTRACT: In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2))], the cyclo-penta-dienyl rings are present in an eclipsed conformation. The imine is E-configured. In the crystal, C-H?N inter-actions involving both N atoms connect the mol-ecules into two undulating sheets perpendicular to the b axis. The centroid-centroid distance between the two aromatic systems in the ferrocenyl moiety is 3.2928?(18)?Å. A C-H?? inter-action is also present.

SUBMITTER: Adams N

PROVIDER: S-EPMC3212159 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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(E)-N-(Ferrocenyl-methyl-idene)(pyridin-3-yl)methanamine.

Adams Nadia N Gerber Thomas T McCleland Cedric C Betz Richard R

Acta crystallographica. Section E, Structure reports online 20110713 Pt 8

In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2))], the cyclo-penta-dienyl rings are present in an eclipsed conformation. The imine is E-configured. In the crystal, C-H⋯N inter-actions involving both N atoms connect the mol-ecules into two undulating sheets perpendicular to the b axis. The centroid-centroid distance between the two aromatic systems in the ferrocenyl moiety is 3.2928 (18) Å. A C-H⋯π inter-action is also present. ...[more]

PMID: 22090861

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