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N-(5-Bromo-pyridin-2-yl)acetamide.

ABSTRACT: The asymmetric unit of the title compound, C(7)H(7)BrN(2)O, contains two mol-ecules, in one of which the methyl H atoms are disorderd over two orientations in a 0.57?(3):0.43?(3) ratio. The dihedral angles between the pyridine rings and the acetamide groups are 7.27?(11) and 8.46?(11)°. In the crystal, mol-ecules are linked by N-H?O and C-H?O hydrogen bonds generating bifurcated R(2) (1)(5) ring motifs, which in turn lead to [110] chains.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3213491 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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N-(5-Bromo-pyridin-2-yl)acetamide.

Fun Hoong-Kun HK Shahani Tara T Kumar Rajesha R Isloor Arun M AM Shivananda Kammasandra N KN

Acta crystallographica. Section E, Structure reports online 20110716 Pt 8

The asymmetric unit of the title compound, C(7)H(7)BrN(2)O, contains two mol-ecules, in one of which the methyl H atoms are disorderd over two orientations in a 0.57 (3):0.43 (3) ratio. The dihedral angles between the pyridine rings and the acetamide groups are 7.27 (11) and 8.46 (11)°. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds generating bifurcated R(2) (1)(5) ring motifs, which in turn lead to [110] chains. ...[more]

PMID: 22091070

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