Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

3-Amino-N'-(2-oxoindolin-3-yl-idene)benzohydrazide.

ABSTRACT: The title compound, C(15)H(12)N(4)O(2), contains two substituted benzohydrazide and indole rings linked via a C=N double bond. The dihedral angle between the benzene ring and the indole ring system is 11.38?(10)°. The mol-ecular structure is stabilized by an intra-molecular N-H?O hydrogen bond, forming a six-membered ring. The crystal structure is consolidated by inter-molecular N-H?O and C-H?O inter-actions, which result in sheets.

SUBMITTER: Jamal RA

PROVIDER: S-EPMC3213601 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

3-Amino-N'-(2-oxoindolin-3-yl-idene)benzohydrazide.

Jamal Rifat Ara RA Ashiq Uzma U Yousuf Sammer S Ain Qurrat Ul QU

Acta crystallographica. Section E, Structure reports online 20110730 Pt 8

The title compound, C(15)H(12)N(4)O(2), contains two substituted benzohydrazide and indole rings linked via a C=N double bond. The dihedral angle between the benzene ring and the indole ring system is 11.38 (10)°. The mol-ecular structure is stabilized by an intra-molecular N-H⋯O hydrogen bond, forming a six-membered ring. The crystal structure is consolidated by inter-molecular N-H⋯O and C-H⋯O inter-actions, which result in sheets. ...[more]

PMID: 22091178

Similar Datasets

N'-(1-Allyl-2-oxoindolin-3-yl-idene)benzohydrazide.

Project description:In the title compound, C(18)H(15)N(3)O(2), the dihedral angle between the ring systems is 15.1?(1)°. The amino H atom is hydrogen bonded to the exocyclic O atom of the five-membered ring, forming an S(6) motif.

| S-EPMC3007202 | biostudies-literature

(E)-N'-[1-(4-Amino-phen-yl)ethyl-idene]benzohydrazide.

Project description:Crystals of the title compound, C(15)H(15)N(3)O, were obtained from a condensation reaction of benzohydrazide and 1-(4-amino-phen-yl)ethanone. The mol-ecule assumes an E configuration with the amino-phenyl and benzohydrazide units located on opposite sites of the C=N double bond. In the crystal structure, the benzene rings of the mol-ecule are slightly twisted with respect to the central hydrazide, the dihedral angles being 18.22 (12) and 27.62 (12)°. The crystal structure contains inter-molecular N-H⋯O and weak C-H⋯N hydrogen bonding.

| S-EPMC2961641 | biostudies-literature

N'-[4-(Dimethyl-amino)benzyl-idene]benzohydrazide.

Project description:In the title mol-ecule, C(16)H(17)N(3)O, the two aromatic rings form a dihedral angle of 4.51?(18)°. In the crystal structure, inter-molecular N-H?O hydrogen bonds link mol-ecules related by translation along the a axis into ribbons.

| S-EPMC2970421 | biostudies-literature

1-(1-Nonyl-2-oxoindolin-3-yl-idene)thio-semicarbazide.

Project description:In the title compound, C(18)H(26)N(4)OS, the imine C=N bond has a Z configuration, whereas the N-N-C=S unit has an E conformation. In the crystal, mol-ecules are connected through N-H?O hydrogen bonds, forming zigzag chains running along the b axis. The nonyl chain adopts an extended zigzag conformation.

| S-EPMC2979500 | biostudies-literature

1-(1-Decyl-2-oxoindolin-3-yl-idene)thio-semicarbazide.

Project description:In the title 1-alkyl-isatin 3-thio-semicarbazone, C(19)H(28)N(4)OS, the imine C=N bond has a Z configuration, whereas the N-N-C=S unit has an E conformation. In the crystal, mol-ecules are connected by N-H?O hydrogen bonds, forming zigzag chains running along the b axis.

| S-EPMC2979634 | biostudies-literature

(Z)-2-(2-Oxoindolin-3-yl-idene)-N-phenylhydrazinecarbothio-amide.

Project description:In the title compound, C(15)H(12)N(4)OS, the dihedral angle between the nine-membered indolin-2-one ring system and the phenyl ring is 2.72 (7)°. Intra-molecular cyclic N-H⋯O and C-H⋯S hydrogen-bonding inter-actions [graph set S(6)] are present, as are weak N-H⋯N inter-actions [graph set S(5)]. In the crystal, mol-ecules form centrosymmetric cyclic dimers through pairs of N-H⋯O hydrogen bonds [graph set R(2) (2)(8)] and these are extended by C-H⋯S inter-actions. The crystal structure also features weak C-H⋯π inter-actions.

| S-EPMC3343940 | biostudies-literature

1-(5-Nitro-2-oxoindolin-3-yl-idene)thio-semicarbazide.

Project description:In the title molecule, C(9)H(7)N(5)O(3)S, there is an intramolecular N-H⋯O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N-H⋯O and N-H⋯S hydrogen bonds, forming two-dimensional networks lying parallel to (10[Formula: see text]). They are separated by an interplanar distance of 3.3214 (9) Å, leading to π-π interactions which stabilize the crystal structure.

| S-EPMC3247594 | biostudies-literature

2-(1-Methyl-2-oxoindolin-3-yl-idene)malono-nitrile.

Project description:The title mol-ecule, C12H7N3O, is almost planar, with an r.m.s. deviation of 0.026 Å. No directional interactions could be detected in the crystal.

| S-EPMC3770372 | biostudies-literature

1-(5-Bromo-2-oxoindolin-3-yl-idene)thio-semicarbazone.

Project description:The title mol-ecule, C9H7BrN4OS, is essentially planar [r.m.s. deviation = 0.066 (2) Å], the maximum deviation from the mean plane through the non-H atoms being 0.190 (3) Å for the terminal amine N atom. In the crystal, mol-ecules are linked through N-H⋯O and N-H⋯S inter-actions, generating infinite chains along the b-axis direction. In turn, the chains are stacked along the a axis via π-π inter-actions [centroid-centroid distance = 3.470 (2) Å] and further connected by N-H⋯Br inter-actions into a three-dimensional network. An intra-molecular N-H⋯O hydrogen bond is also observed.

| S-EPMC3793752 | biostudies-literature

4-(3-Methoxy-phen-yl)-1-(2-oxoindolin-3-yl-idene)thio-semicarbazide.

Project description:In the title compound, C(16)H(14)N(4)O(2)S, intra-molecular N-H?N hydrogen bonding forms an S(5) ring, whereas N-H?O and C-H?S inter-actions complete S(6) ring motifs. In the crystal, mol-ecules form inversion dimers due to N-H?O inter-actions. The dimers are inter-linked through N-H?S hydrogen bonds and ?-? inter-actions occur with a centroid-centroid distance of 3.8422?(11)?Å between the meth-oxy-containing benzene ring and the five-membered heterocyclic ring.

| S-EPMC2979529 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data