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Catalytic enantioselective diboration of cyclic dienes. A modified ligand with general utility.

ABSTRACT: The enantioselective 1,4-diboration of cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4-diol, whereas homologation can be used to deliver a chiral 1,6-diol.

SUBMITTER: Hong K 

PROVIDER: S-EPMC3219059 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Catalytic enantioselective diboration of cyclic dienes. A modified ligand with general utility.

Hong Kai K   Morken James P JP  

The Journal of organic chemistry 20110920 21

The enantioselective 1,4-diboration of cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4-diol, whereas homologation can be used to deliver a chiral 1,6-diol. ...[more]

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