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Barium manganese(II) selenostannate(IV), BaMnSnSe(4).


ABSTRACT: The title compound, BaMnSnSe(4), was obtained by reaction of the elements at 1123?K in an evacuated silica tube. It adopts the BaCdSnS(4) structure type, which is a variant of the SrIn(2)Se(4) structure type. Its structure consists of distorted edge-sharing tetra-hedra, alternating with Mn and Sn atoms as central atom. These [MnSnSe(6)] units display corner sharing, forming stacked infinite layers in the ac plane. The three different Ba(2+) atoms are located between the [MnSnSe(6)] layers, two on twofold rotation axes, and exhibit distorted square-antiprismatic coordinations.

SUBMITTER: Assoud A 

PROVIDER: S-EPMC3238579 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Barium manganese(II) selenostannate(IV), BaMnSnSe(4).

Assoud Abdeljalil A   Kuropatwa Bryan A BA   Kleinke Holger H  

Acta crystallographica. Section E, Structure reports online 20111116 Pt 12


The title compound, BaMnSnSe(4), was obtained by reaction of the elements at 1123 K in an evacuated silica tube. It adopts the BaCdSnS(4) structure type, which is a variant of the SrIn(2)Se(4) structure type. Its structure consists of distorted edge-sharing tetra-hedra, alternating with Mn and Sn atoms as central atom. These [MnSnSe(6)] units display corner sharing, forming stacked infinite layers in the ac plane. The three different Ba(2+) atoms are located between the [MnSnSe(6)] layers, two o  ...[more]

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