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Catena-Poly[[manganese(II)-tris-(?-bet-aine-?O:O')] tetra-bromido-manganate(IV).

ABSTRACT: The title compound, [Mn(C(5)H(11)NO(2))(3)]·MnBr(4), contains polymeric cationic chains of distorted MnO(6) octa-hedra and bridging betaine mol-ecules, running parallel to the a axis. There are two distinct Mn(2+) cations in the chain, both with site symmetry . Distorted [MnBr(4)](2-) tetra-hedra occupy the spaces between the chains.

SUBMITTER: Kocadag M

PROVIDER: S-EPMC2959294 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[manganese(II)-tris-(μ-bet-aine-κO:O')] tetra-bromido-manganate(IV).

Kocadag Maria M Fleck Michel M Bohatý Ladislav L

Acta crystallographica. Section E, Structure reports online 20080917 Pt 10

The title compound, [Mn(C(5)H(11)NO(2))(3)]·MnBr(4), contains polymeric cationic chains of distorted MnO(6) octa-hedra and bridging betaine mol-ecules, running parallel to the a axis. There are two distinct Mn(2+) cations in the chain, both with site symmetry . Distorted [MnBr(4)](2-) tetra-hedra occupy the spaces between the chains. ...[more]

PMID: 21201024

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